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姚小泉
姓名: 姚小泉 性别: 职务:
职称: 教授 导师类别: 博士生导师 办公室: 材料楼439
研究领域: 有机功能材料,绿色合成与催化,精细有机合成,金属有机化学,
电话: 13584000538 Email: yaoxq@nuaa.edu.cn
个人简介

姚小泉教授2000年毕业于中科院大连化物所,获有机化学理学博士学位; 2001-2003年中科院上海有机所博士后, 03年被评为副研究员;2003-2006年加拿大McGill大学博士后;2006年3月起在南京航空航天大学从事有机化学领域的教学、科研工作,同年获聘为教授; 09年11月,被评为博士生导师。美国化学会会员。研究工作中以有机功能材料和具有生理活性的有机化合物合成中所涉及的关键反应为主要研究对象,着重开展在绿色溶剂体系中的催化有机合成研究、发展新的绿色催化材料和催化合成体系。

近年主持国家自然科学基金三项,省自然基金及教育部留学归国基金各一项。先后发表SCI论文三十余篇;获发明专利两项,省级科研鉴定成果一项。其主要代表作得到相关研究者的普遍关注,单篇最高引用200余次。

学术成果

代表性文章:

1) Wei Lv, Jing Tian, Nan Deng, Yan Wang, Xiaoshu Zhu and Xiaoquan Yao* “Dual-immobilized copper catalyst: carbon nitride-supported copper nanoparticles catalyzed oxidation of propargylic alcohols” Tetrahedron Lett. 2015, 56, 1312-1316.

2) Weijiang Sun, Yan Wang, Xuan Wu, Xiaoquan Yao*, “Palladium-, ligand-, and solvent-free synthesis of ynones by the coupling of acyl chlorides and terminal alkynes in the presence of a reusable copper nanoparticle catalyst” Green Chem., 2013, 15(9), 2356-2360,.

3) 喻敏,韩成燕,王勇,朱荔,姚小泉*, “IB族金属纳米颗粒在有机合成反应中的应用” 有机化学, 2013, 33(03), 492-503.

4) Min Yu, Yong Wang, Weijiang Sun and Xiaoqaun Yao* “A Mild, Highly Efficient Addition of Alkynes to Aldehydes Catalyzed by Titanium Dioxide-Supported Silver Nanoparticles” Adv. Synth. Catal., 2012, 354(1), 71-76.

5) Chengyan Han, Min Yu, Weijiang Sun and Xiaoquan Yao* “Ligand-Promoted, “Copper Nanoparticles Catalyzed Oxidation of Propargylic Alcohols with TBHP or Air as Oxidant”, Synlett., 2011, 16, 2363-2368.

6) Mingdeng Lin, Min Yu, Chengyan Han Chao-Jun Li * and Xiaoquan Yao* “A Water-Promoted, Silver-Phosphine Complex-Catalyzed Stereoselective Cyclization of 2-(1-Hydroxy-3- arylprop-2-ynyl)phenols Leading to a Highly Efficient Approach to Aurones” Synth. Comm. 2011, 41, 3228

7) Min Yu, Mingdeng Lin, Chengyan Han Chao-Jun Li* and Xiaoquan Yao* “Ligand-Promoted Reaction on Siliver Nanoparticles: Phosphine-Promoted, Silver Nanoparticle-Catalyzed Cyclization of 2-(1-Hydroxy-3-Arylprop-2-ynyl) Phenols” Tetrahedron Lett. 2010, 51, 6722-6725

8) Min Yu, Ying Wang, Chao-Jun Li, Xiaoquan Yao* “Pybox ligand-promoted copper(I)-catalyzed three-component tandem coupling-annulation of terminal alkynes, amines and ortho-alkynylaryl aldehydes”Tetrahedron Lett. 2009, 50, 6791-6794

9) Min Yu, Rachid Skouta, Lei Zhou, Huan-feng Jiang, Xiaoquan Yao *, Chao-Jun Li “Water-Triggered, Counter-Anion-Controlled, and Silver-Phosphines Complex-Catalyzed Stereoselective Cascade Alkynylation/Cyclization of Terminal Alkynes with Salicylaldehydes” J. Org. Chem. 2009, 74, 3378 -3383

10) Clara I. Herrerías, Xiaoquan Yao, Zhiping Li, and Chao-Jun Li* “Chemical Transformations Based on the Reactions of C-H Bonds in Water” Chem. Rev. 2007, 107, 2546-2562

11) Xiaoquan Yao and Chao-Jun Li* “Water-Triggered and Gold(I)-Catalyzed Cascade Addition/Cyclization of Terminal Alkynes with ortho-Alkynylaryl Aldehyde” Org. Lett. 2006, 8, 1953 -1956

12) XiaoquanYao and Chao-Jun Li "Phosphine-Triggered Complete Chem-Switch Efficient aldehyde-Alkyne-Amine Coupling to Efficient Aldehyde-Alkyne Coupling in Water" Org. Lett. 2005, 7, 4395

13) Xiaoquan Yao and Chao-Jun Li* “Highly Efficient, Reversible Addition of Activated Methylene Compounds to Alkenes Catalyzed by Silver Catalysts” J. Org. Chem. 2005, 70, 5752-5755

14) Rene-Viet Nguyen, Xiaoquan Yao, D. Scott Bohle and Chao-Jun Li* “Gold and Silver-Catalyzed Highly Regioselective Addition of Active Methylenes to Dienes, Trieneand Cyclic Enol Ethers” Org. Lett. 2005, 7, 673-676

15) Xiaoquan Yao and Chao-Jun Li* “Highly Efficient Addition of Activated Methylene Compounds to AlkenesCatalyzed by Gold and Silver” J. Am. Chem. Soc. 2004, 126, 6884-6885

承担项目

主持国家自然科学基金:

1) “氮掺杂介孔碳材料作为新型固定化配体在金属催化的合成反应中的应用”,

面上项目,2015-2018

2)“配体修饰下IB族金属纳米颗粒催化的有机合成反应”,

面上项目,2012-2015;

3)“水相或离子液体中IB族金属催化的碳碳键形成反应”,

青年基金项目,2007-2009;

主持江苏省基金:

基于新型桥联配体的电致发光材料研究 2008-2010


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